Nucleophilic Reactivity. Part 8. Reactivity of Alkoxide Ions, Alcohols, and Water Toward Picryl Fluoride.
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Nucleophilic reactivity of copper(ii)-alkylperoxo complexes.
Copper(ii)-alkylperoxo adducts, [Cu(CHDAP)(OOR)]+ (CHDAP = N,N'-dicyclohexyl-2,11-diaza[3,3](2,6)pyridinophane; R = C(CH3)2Ph and tBu), were prepared and characterized using various physicochemical methods. These are the first synthetic Cu(ii)-alkylperoxo complexes that can perform aldehyde deformylation (i.e., nucleophilic reactivity) under the stoichiometric reaction conditions, which was con...
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ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1966
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.20-0303